Forgot the link but here are the instructions for Outlook 2013 on Windows 7:
Starting with Outlook 2013, the registry key has changed to HKEY_CURRENT_USER\Software\Microsoft\Office<version>\Outlook\Profiles
and to save your signatures follo these instructions to save them:
Signatures These are stored in a Signatures folder, which will contain a bunch of sub-directories
and files with the information Typically called: Signatures (folder)
Typically found at: C:\users\Username\appdata\Roaming\Microsoft\Signatures
.
To complete the picture, saving rules and other settings you have changed save these folders:
C:\users\Username\appdata\Roaming\Microsoft\Outlook
C:\users\Username\appdata\Roaming\Microsoft\Templates
C:\users\Username\appdata\Roaming\Microsoft\Signatures (mentioned here again)
.ost files for Outlook: C:\Users\username\AppData\Local\Microsoft\Outlook
.pst files for Outlook: C:\Users\username\Documents\Outlook Files
Once again this is for Office 2013 Outook in Windows 7 Professional. The registry key is in a different location for 2010 and prior, I believe. For the email account settings you do not have to back up any files, just Export that one key and Import it after
installing 2013 on new machine. I would do it before opening Outlook for the first time. Then after opening it you can point each mail account to its own .pst account. If it is an account that stores email and folders on the server, that is the best. You don't
have to import anything. Hope this helps you out...