Using classic Outlook for Windows in business environments
I would first make sure the accounts are removed from Outlook before you delete the OST files from the IMAP accounts. Click File, Account Settings, Account Settings, and remove those that are redundant.
You might wait some time before deleting the OST files to make sure you were not using them. If you were using them, you can add the accounts back in Outlook (File, Add Account).
The OSTs are here, C:\Users<account>\AppData\Local\Microsoft\Outlook.
The PSTs are here C:\Users<account>\Documents\Outlook Files