Using Classic Outlook on Windows for personal email, calendar, and contact management
Hi Johnny,
I'd like to suggest you to check two places regarding the issue.
First one - Admin center> Users> Active users> The user in question and check whether under Username/ E-mail you have onmicrosoft or your domain.
Exchange admin center> Recipients> Mailboxes> The mailbox in question> Email address. Here you will find at least 2 SMTP email addresses - one with your domain and the second with onmicrosoft.com. Bold one is default. If onmicrosoft is bold, doubleclick the one with your domain and select the option Make this the reply address.
Best regards,
Nemanja