Hi Thomas,
By checking the escalated case, good to know that the issue is solved by following the workaround below. We’d like to share the workaround here to benefit other community members:
Issue Description:
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The server you are trying to access is using an authentication protocol not supported by this version of Office.
Workaround:
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1. End the GROOVE and MSOSYNC processes.
2. Open Word / Excel / PowerPoint (or any Office app that is not OneDrive For Business).
3. Click the Switch Account at the top right.
4. Click Add Account.
5. Add the account that you actually need to sync that particular library.
6. Close the application.
7. Close OneDrive for Business. (You need to actually right click in the taskbar and click Exit).
8. Open OneDrive, and attempt to sync the library. You should not be prompted with the error message.
* If these steps do not work, please remove all signed in accounts, and then attempt to sync the library which should prompt appropriately. After the library syncs, feel free to add those identities back.
Again, appreciate your working with us.
If this helps you, please let us know by marking "Yes" the post which was helpful, or answered the question.
Thanks,
Lingyu Sun