This is a common problem. Please try the following steps.
1- First make hidden files and folders visible. Go to control Panel/folder options/View tab/check to show hidden files and folders.
2- Go to C:\ProgramData\Watchtower\WTLibrary
3- delete the two files, "ca-bundle.zip" and "cert.pem"
4- Open Watchtower Library, go to help/check for updates and try again.
If you have any problems then try uninstalling the programme. Reboot and check that those two files have been deleted. Then try reinstalling again. If you get the same error message then repeat steps 1-4
I hope this helps.
Kind regards
Chris