Have you tried to:
- Get all available updates from Windows Update
- Kill the Skydrive processes (there are two, one for files sync and the other for settings)
- Delete the AppData\Microsoft\Windows\Skydrive folder (all of it)
- Delete your Skydrive folder (or move its contents to a different location if you are not sure you have everything on the cloud)
- Run the Skydrive Troubleshooter I posted above
?
If not, give it a try, just in case :)