Processes in Microsoft 365 for setting up Office apps, redeeming product keys, and activating licenses.
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The message "This product key was used with a different account” normally means that the key was redeemed previously and is already associated with a Microsoft account. A redeemed Office key is generally used only once. After redemption, Office 2016 should be installed and activated by signing in with the Microsoft account originally associated with the purchase, rather than by entering the key again.
Please try the following:
- Sign in to the Microsoft account Services & subscriptions page using the Microsoft account that was used when Office was first activated.
- If necessary, check any other personal Microsoft accounts or older email addresses you may have used in 2015 or 2016.
- If Office Home & Student 2016 appears, use the installation option shown there, then open Word or Excel and sign in with that same account.
- If the product does not appear under any account, contact Microsoft Support and request help with Office product activation and identifying the account associated with a redeemed retail key. Keep the original box, product-key card, and proof of purchase available, but share them only privately with the support agent.
Microsoft Q&A is a public forum, so moderators here cannot inspect the product key, verify its activation history, identify the account to which it belongs, or manually reactivate it.
Please also note that support for Office 2016 has ended. This does not by itself convert a one-time-purchase license into a subscription, but Office 2016 no longer receives security updates or technical support.
Thank you for your understanding and time