Hi,
I found a different solution that worked for me. First I went to "Credential Manager" in the control panel and removed all the references to the email accounts in question (had two emails that reused to add to the new Outlook), after I went to my microsoft online settings for each account, in "Your Info" > "Sign-In Preferences", to have a look at what alias I had in there, but I didn't have any, was just using my regular email address and set as primary, so I decided to create a new temporary alias and login with that in the new Outlook app.
This failed on the first account but when I loged in again (on that account) but using the previous alias it worked!
I then tried doing the same process with the second account, and logged in with the alias which is this case worked straight away,
I guess adding that alias forced some refresh on the account sign-in preferences that allowed it to work after.
Since using this app as a beta it had never worked! I now have both accounts added and they show the old primary alias that I always had.