Using classic Outlook for Windows in business environments
This worked for me.
Cause: My Mircosoft Live account had my Gmail account set as it's primary alias. Plus, I had already set up my Gmail account in the New Outlook. When I tried adding my Outlook email account, it was trying to add a Gmail address to New Outlook which already contained a Gmail address.
Solution: Log in to Microsoft at account.microsoft.com/profile and under the heading"Account info" click on "Edit Account Info". Then next to your outlook.com address click on "make primary". If you return to New Outlook and try to add your outlook email address, it should now work.
Thanks for your help - problem solved.
I have a btinternet.com mail account and New Outlook now displays my mail, contacts and events. So simple why do Microsoft not suggest this solution.