Using the New Outlook for Mac for personal email and calendar
Hello Mark Penwarden,
Just to clarify, what type of email account are you using in Outlook for Mac, for example Outlook.com/Microsoft 365, Gmail, or another provider?
I ask because the available junk-mail controls differ depending on the account type.
Also, if your main goal is to stop these messages from filling the Junk folder, blocking the domain may not achieve that. Outlook's blocked-sender feature generally classifies blocked mail as junk rather than preventing it from arriving.
Once you confirm the account type, I can point you to the appropriate option.