Using New Outlook on Windows for personal email, calendar, and contact management
Since it is their email service that is having an issue, and additionally they have a feature missing in the interface, it clearly indicates Outlook is not at fault here. You should contact Comcast for further assistance.
https://www.xfinity.com/support/contact-us
You may ask them that you need help generating an app password.
Standard 3rd party link disclaimer:
There may be links to non-Microsoft websites that provide accurate and safe information. Watch out for ads on websites frequently classified as PUP (Potentially Unwanted Products). There is no need to buy paid products to fix your computers, as they sometimes do more harm than good.