Hi @Gardner, Drew
Thank you for sharing your concern.
Based on my research, this issue might be related to how Microsoft Entra ID evaluates Exchange recipient attributes for mail-enabled objects in a hybrid Exchange environment. As far as I know, the primary email address shown in Microsoft Entra ID is not determined solely by the mail attribute in Active Directory. Instead, Entra ID evaluates Exchange recipient attributes together, with proxyAddresses typically taking precedence. If a Mail User has a primary SMTP address defined in proxyAddresses, Entra ID may use that address as the primary email address, while the value from the mail attribute may appear as an additional address.

You can refer more via: How the proxyAddresses attribute is populated in Microsoft Entra ID | Microsoft Learn
To ensure I fully understand your situation and provide the most effective assistance, I’ll need a few additional details, such as:
Could you confirm whether the affected object is an Exchange Mail User or another recipient type?
May I know the values of these Active Directory attributes for one affected user? (such as mail, proxyAddresses, mailNickname, and userPrincipalName)
If possible, please also share the output of this command:
Get-MailUser <Identity> | Format-List PrimarySmtpAddress, ExternalEmailAddress, EmailAddresses, EmailAddressPolicyEnabled, RecipientTypeDetails
In order to better assist you, I will open a private message within this thread. Please share the output of your AD attributes from your side so I can better understand the issue. This approach helps to protect your personal information and prevents sensitive information from becoming publicly visible.
To view or send private messages, please sign in to the Microsoft Q&A forum with the account that was used to create this thread, and then select "Private messages"

Any updates would be greatly appreciated.
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