An integrated threat protection solution designed to detect, investigate, and respond to cyber threats across Microsoft 365 services.
Hello lespaulio, my name is Emmanuel.
I am so sorry to hear that you are having an issue signing in to your child's account with Microsoft Defender for Android. Kindly uninstall the Microsoft Defender app from the device of your child then go to this link https://aka.ms/AndroidDefender and install it from there then log in with your child's account.
Please also make sure that your child's email address you are trying to log in to is purely associated with the Microsoft Family account. Please check the spelling carefully.
On your child's Android device, please also go to the main SETTINGS > ACCOUNTS AND BACK UP > MANAGE ACCOUNTS > scroll down from the list of accounts that are currently logged in to your child's Android device and look for the Microsoft account and please make sure no Microsoft account is associated with work or school account. If there is, try signing out first from your work or school account on your child's device then log in to Microsoft Defender using your child's Microsoft Family account.
Hope this information can help you.
Let me know if this works for you.