An integrated threat protection solution designed to detect, investigate, and respond to cyber threats across Microsoft 365 services.
Maybe you should try disabling first the Google Family Link temporarily then log in on the Microsoft Defender app on your child's devices then once successfully logged in on the Defender app then re-enable the again the Google Family Link.
If my suggestion above didn't work, I would suggest contacting the developer of the Defender app on the Google Playstore by searching Microsoft Defender from the Playstore and then clicking DEVELOPER CONTACT's email address atpandr@microsoft.com or leave feedback by rating the app.