A family of Microsoft relational database management systems designed for ease of use.
Just to give everybody a heads up. Our company also discovered this problem with exporting to PDF in .accdr files and Access 2016. We went through the same troubleshooting steps as everybody else in this thread and discovered the issue was new in 2016 and the export process worked fine in Access 2010/2013. We created a test database from scratch to test not only the function, but also using the pdf export button in the Access 2016 ribbon. In both instances Access crashes after its been open a certain amount of time. As another posted indicated, the MSI and earlier click to run versions seem to crash much earlier while the more recent builds appear to crash after Access has been open between 1-2 hours.
We opened a paid support ticket with Microsoft Support and after going through several levels of support over the course of several weeks, the Office VBA Support team confirmed this is a bug and it will be fixed at some point in the future. The support fee we paid was refunded because it was a confirmed bug.
We were told an ETA could not be provided, but we were told it was confirmed to be a bug and was added to their database of bugs to fix.