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It's a work in progress in conjunction with the move of Outlook.com to the Exchange Online platform. Once that is completed and your account has been migrated, sending from an alias address will be possible without any additional configuration in Outlook 2010 or later.
Until then, you can configure the alias as an additional POP3 account and configure it for sending only.
Hi
When you talk about a "work in progress", do you mean that in the future it will be possible to send a message with Outlook 2016 from a default alias address that is not the primary alias ?
For the time being, it seems not to be possible:
Due to the upgrade of outlook.com to Exchange online, I had to change the account parameters in Outlook 2016 to an Exchange account, based on an ...@outlook.com primary alias, and the emails can be sent only from this primary alias.
Regards