A family of Microsoft word processing software products for creating web, email, and print documents.
You are not bugging me - but our ability to help without access to the PC is limited.
You appear to have created a folder, not as a sub folder of Startup but as a sub folder of Word. This contains a raft of files beginning ~WRL. All the files in that folder (and the folder itself) can be deleted. They are serving no useful purpose.
The folders I suggested you create were sub folders from My Documents, for you to use these rather than store documents on the desktop,
Do not keep ANY files that begin with ~$ when Word is closed. These are orphan lock files and should not be present.
In your final illustration, (the Templates folder) although there are several files which appear to be superfluous, they are not interfering with the process so can remain