Using New Outlook on Windows for professional communication and productivity
That's a great workaround!
As a slight variant, I found that it's not even necessary to edit the start and end time in the Scheduling Assistant tab. For me the following also works:
Open the appointment for editing, so we are in the "Appointment" tab. Now flip to the Scheduling Assistant tab and without doing anything there immediately go back to the Appointment tab. Now I can edit Reminder, Start time and End time in the Appointment tab without any issues and save them.
Still annoying that two extra clicks are necessary though!