Using New Outlook on Windows for professional communication and productivity
That's unfortunate.
In this case, you need to do the following:
- New rule
- Allow, everyone
- Publisher
- Select any app already installed
- Slide that cursor to the top so that there will only be *
- Add exception and select outlook
- Finish
After reboot it will block installation of new Outlook permanently (occasionally it will nag at boot about an app blocked by an administrator but you can close it when it happens)