Using Classic Outlook on Windows for personal email, calendar, and contact management
Gabriel,
It appears that creating a new Outlook profile doesn't always eliminate the problem. I have a number of accounts and a number of Outlook rules on several, so creating a new profile is a tedious process.
Further, elsewhere there are reports that claim this error occurs when a Google Apps Sync for Outlook and an Exchange Server account are configured in the same profile. See: https://docs.microsoft.com/en-us/outlook/troubleshoot/profiles-and-accounts/operation-failed-send-email-outlook
It turns out that I don't use Google Apps Sync for Outlook, so that isn't my problem. But since you didn't know that, I am even more skeptical that you have a full grasp of the problem. I am not trying to be rude here, but while I will be pleased to help Microsoft isolate the cause of it reporting an "unknown error" that is at best a mis-feature. I am reluctant to go through something that is, at best, going to make the error disappear in this one instance, but not get to the fundamental cause.