Using Outlook for Android in business environments for email and scheduling
I am also having this problem. I have an android tablet with Jellybean. I can sync just fine with my contacts via outlook.com, but when I want to add a new contact, I get presented the message "Your new contact will be synchronized with my gmail account (which I never use). I have the two choices of OK or add a new account. But, the only two options I have under add a new account is "google" or "corporate". Then, I can go through the steps of setting up a new exchange account.
I've turned off syncing contacts for gmail in the system settings/account settings. And, I've gone ahead and added a contact to see if it would sync with outlook.com. I figured, if I got the contact in the contact database, it might just go ahead and sync with outlook, but this did not work.
But, I finally tried "Contact Editor Free" available on Google Play. The way this works is when you choose to add a new contact from "People" (the address book that came with my android), you can choose to use the contact editor and then you can choose to create the contact under my outlook.com account.
This works, but is not really elegant. I'd rather create the contact straight from my address book. But it works just fine. If anyone has a better idea, I would appreciate your responses.