>> what is the "file sync software" <<
The software is Free File Sync and while it's design, functionality, options and capabilities are excellent, imho, the "Free" and the payment options are misleading, so, I am not recommending it. It is better than any of the many other file sync programs that I have researched and/or tested.
That, however, is moot. My observation is that any file transfer action such as manually transferring a file using file explorer from the Win8.1 computer would have probably triggered Win10 to allow connections in the other direction. Again, I am now more certain than ever that this is a user rights glitch within Win10.
I'm guessing that there are not that many users out there that don't login with admin rights if they have that option. Logging normally in normally with non admin rights does give one at least a tad more sleep at night ;-)
Beverly