Hi and thanks for reaching out. My name is William. I'm a Microsoft Windows Certified Professional and Systems Administrator. I'll be happy to help you out today.
"...it's unable to boot from USB." Why? All modern computer should be able to boot from USB, otherwise there would be no way to install the OS. To create Windows 10 installation boot media, see this Microsoft article: https://www.microsoft.com/en-us/software-downlo.... Afterwards, go into the BIOS and change the boot order to move USB to the top of the list or use quick boot option. https://www.asus.com/support/FAQ/1030858/