Been bashing my head against this for weeks.
The FQDN v IP address 'fix' works for a day or two, then stops and you have to change to the other method to get it to reconnect, even after removing the drive mappings. You can't even browse to access the NAS. There is no Windows server in this network, just five W10 workstations and a NAS, so solutions involving Domain Server/Windows File Server 'fixes' are irrelevant. I've also discovered that a Linux box plugged into the LAN temporarily has no such issues.
I've tried re-enabling SMB 1.0 (which I need anyway as our PXE 'server' (on one of the workstations) doesn't play at all without it, so it's back on all of them and the autoremove has been shot in the head.
Tried the various registry tricks. At first, they seem to work, then after a few reboot, suddenly it's lost the plot again and nothing short of removing the mappings and reconnecting via IP if it was using FQDN and using FQDN if it was using IP will restore connectivity. Win 10 20H2 does NOT change this issue in any way, shape or form. It remains intermittently popping up on reboot. This has become a major issue as we are in the process of moving user directories (Documents, Pictures, Videos, Desktop and their Outlook .pst file to the NAS. This has meant several reboots to try and get it to find the desktop! This is using a full path to the file, not the mapped drive letter, ie //NAS1/Storage/Manager/Desktop not H:\Desktop. So the underlying network connection to the Synology NAS is not being restored.
If anyone has suggestions (aside from ditching Windows) I'd be pleased to hear from them.
Geoff