I got a chance to perform some more in-depth analysis of the network types that work and do not work and also verify the workaround presented by user PhilippZeile.
The issue of course occurs if you are using offline files/folder redirection. If you are not connected to a network that will allow offline sync the computer will bsod immediately after initial sign-in. Connecting via wired or wifi connection will bypass the issue, so long as you are connected to a network that can offline sync, including pre-sign in VPN. Connecting to any other network will still fail. The issue therefore appears to be prompted by a failure to be able to offline sync.
The workaround presented by PhilippZeile will work if you are unable to access a valid network: sign-in as a local user, then sign out and your normal user account will work properly whether you are on the network or not.
I'm checking whether completing a full offline sync resolves this issue. I'm hoping so, because this issue has seemed to occur more for existing users getting emplacement computer (and therefore having more offline files to sync) vs new users that have nothing to sync.
EDIT: completing a full offline intial sync does not help, so the only workarounds are to be connected to a sync-capable network or first logging in with a local account.
I've found, no matter the sync amount, I still get a BSOD on sign on. However, if I'm connected to ANY network, phone hotspot, public WIFI, etc., it will NOT BSOD. My issue only happens when i have absolutely no network connectivity what so ever, upon network logon.
I may try the Insider Ring to see if it fixes the issue