OK so the good news? I got Windows 8.1 to install! Following some advice in this thread, I uninstalled my entire catalyst control center along with drivers and whatnot before going forward with the 8.1 install. That seemed to do it, the install went in, and I got all the way to configuring my account and preparing to log in. Then Mr. BSoD came knocking again. But this time he wasn't so friendly.
Since the install had technically completed, this blue screen didn't cause a roll back. Instead my computer restarted, got to the 8.1 login, and blue screened again. Windows automatically started the recovery partition, but when I did a disk check (green to go) and startup recovery (could not recover). Lost at what else to try, I popped in my Acronis CD and ended up having to restore off a drive image I made last night.
In every instance the BSoD told me the same thing: "Bad Pool Header". Unfortunately because I was a little out of it, I forgot to boot into safe mode and check out the logs before doing an image restore. Looking up the Bad Pool Header issue, I think this case is related to drivers given the problems I was having getting past the installation of 8.1. My guess is that the AMD catalyst drivers I had were preventing the 8.1 install from going in, but there's another set of drivers on my system that allows 8.1 to go in but disagrees with it thereafter.
I guess I'm stuck waiting for driver updates from manufacturers or a fix from Microsoft...