There are two different things going on here:
For Win 7 and win 8 when u get the error that applies to a specific file or parse point not being backed up it usually means some file is in quarntine by a virus program and therefore can not be read. There are various possible solutions most center around deleting everything from quarantine. Before you do the back up.
For Win 8 only: The Win 7 back up program included with win 8 does not support backing up a image file to any kind of NAS device (UNIX, Linux) . Internally the program gives an error that the NAS device has an incompatible sector mapping type. You can backup to a hard drive that is attached to a different windows machine and then back up that file to your NAS. Convoluted, but it works. Should MS fix this? Probably yes but their current philosophy seems to be that people should be using win 8 backup (Files within Libraries only) I hate the whole concept of Libraries, (and Play Lists) They make no G D sense to me. But that's just me.
Ich kann auch auf Deutsch eklären. Aber ich glaube es ist bei dir nicht nötig. Dies hat mir auch Länge frustriert.